The role of interlayer adhesion in graphene oxide upon its reinforcement of nanocomposites
نویسندگان
چکیده
Graphene oxide (GO) has become a well-established reinforcement for polymer-based nanocomposites. It provides stronger interfacial interaction with the matrix when compared with that of graphene, but its intrinsic stiffness and strength are somewhat compromised because of the presence of functional groups damaging the graphene lattice and increasing its thickness, and its tendency to adopt a crumpled structure. Although the micromechanics of graphene reinforcement in nanocomposites has been studied widely, the corresponding micromechanics investigations on GO have not been undertaken in such detail. In this work, it is shown that the deformation micromechanics of GO can be followed using Raman spectroscopy and the observed behaviour can be analysed with continuum mechanics. Furthermore, it is shown that the reinforcement efficiency of GO is independent of its number of layers and stacking configurations, indicating that it is not necessary to ensure a high degree of exfoliation of GO in the polymer matrix. It also demonstrates the possibility of increasing the concentration of GO in nanocomposites without sacrificing mechanical reinforcement efficiency. This article is part of the themed issue 'Multiscale modelling of the structural integrity of composite materials'.
منابع مشابه
Preparation of high performance PP/ reduced graphene oxide nanocomposites through a combined in situ polymerization and masterbatch method
Despite the great potential of graphene as a nanofiller, achieving homogeneous dispersion remains the key challenge for effectively reinforcing polyolefin (such as polyethylene (PE) and polypropylene (PP)) nanocomposites. Therefore, in this research, we report a facile combined in situ polymerization and masterbatch method for fabricating PP/reduced graphene oxide (rGO) nanocomposites. In the p...
متن کاملMorphological investigation of Graphene Oxide/ Polyacrylamide super-elastic nanocomposite by a solution polymerization process with enhanced rheological property and thermal conductivity
A series of Graphene Oxide/ Polyacrylamide (GO/PAM) super-elastic nanocomposites with different amounts of Graphene Oxide Nanosheets (GONSs) (0.5, 1, 1.5, and 2 wt. %) were synthesized using an in-situ polymerization in an aqueous medium in this paper. To this end, we proposed a method for obtaining super-elastic nanocomposites with a high dispersion of GONSs in the PAM chains as well as in a r...
متن کاملIn-situ synthesis and characterization of reduced graphene oxide –Ag nanocomposites
Reduced graphene oxide(rGO)–silver(Ag) nanocomposites have been prepared by using solution based facile one-pot synthesis process. The reaction process involves high-temperature liquid-phase exfoliation of graphite oxide and silver acetate in presence of N-N’dimethylformamide (DMF) solvent, resulting in simultaneous formation of rGO as well as Ag nanoparticles. Different nanocomposites have bee...
متن کاملSynthesis and Characterization of Graphene-ZnO Nanocomposite and its Application in Photovoltaic Cells
In this paper, we present a simple method for preparation of graphene-ZnO nanocomposites (G-ZnO). The method is based on thermal treatment of the graphene oxide (GO)/ZnO paste which reduces the graphene oxide into the graphene and leads to the formation of the G-ZnO nanocomposite. The structure, morphology and optical properties of synthesized nanocomposites are characterized with XRD, FESEM, F...
متن کاملEnhanced electrical conductivity properties of Graphene Oxide nanocomposites functionalized with Polyvinyl Alcohol
We report the synthesized and preparation of graphene oxide (GO) nanocomposite functionalized with polyvinyl alcohol (PVA) with different concentration of graphene oxide 0, 1, 1.5, 2, 2.5, 3, 3.5 and 4% weight. This synthesized confirmed by FT-IR. The electrical conductivity of the all nanocomposite was measured at 25°C for all samples and the resulted showed electrical conductivity ...
متن کامل